Journal of Molecular Structure p. 231 - 236 (2017)
Update date:2022-08-12
Topics:
Muche, Simon
Levacheva, Irina
Samsonova, Olga
Biernasiuk, Anna
Malm, Anna
Lonsdale, Richard
Popio?ek, ?ukasz
Bakowsky, Udo
Ho?yńska, Ma?gorzata
Studies of the stability of a ligand derived from L-glutamic acid and ortho-vanillin and its new [Cu4] complex are presented. The [Cu4] complex contains a heterocubane [CuII4O4] core and pendant carboxylic groups increasing its solubility in water, also under basic conditions. The stability of the complex in different solvents is confirmed with ESI-MS studies and such experiments as successful recrystallization. The complex is stable also under physiological conditions whereas the ligand is partly decomposed to L-glutamic acid and ortho-vanillin.
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