Journal of Organometallic Chemistry p. 131 - 138 (1985)
Update date:2022-08-11
Topics:
Bordeau, M.
Djamei, S. M.
Calas, R.
Dunogues, J.
In the presence of catalytic amounts of AlCl3, the chlorosilanes MeSiCl3, ClMe2SiCH2Cl and PhSiCl3 convert Me4Si into Me3SiCl.In the first case, at 130 deg C, two by-products from the industrial synthesis of Me2SiCl2 provide the useful Me3SiCl as the unique product with a 44percent conversion ratio from Me4Si.From ClMe2SiCH2CL, the only products formed are Me3SiCl and Me3SiCH2Cl, which is a useful reagent for organic syntheses (formation ratio: 32percent), if the reaction is performed under atmospheric pressure, but if an autoclave is used EtMe2SiCl (88percent maximal yield) is obtained.
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Doi:10.1039/c19680001272
(1968)Doi:10.1039/C8RA08338J
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(1968)