Full Paper
[8] L. Y. Chen, X. D. Chen, H. L. Liu, Y. W. Li, Small 2015, 11, 2642.
[9] Q. H. Yang, Q. Xu, S. H. Yu, H. L. Jiang, Angew. Chem. Int. Ed. 2016, 55,
3685–3689; Angew. Chem. 2016, 128, 3749–3753.
[10] W. N. Zhang, G. Lu, C. Cui, Y. Liu, S. Li, W. Yan, C. Xing, Y. R. Chi, F. W.
Huo, Adv. Mater. 2014, 26, 4056.
Catalytic Reduction of the Nitro Compound: UiO66@RGO-Pd
(20 mg) was placed in a 5-mL glass reactor, followed by the addition
of ethanol (1 mL), the nitro compound (0.1 mmol) and NaBH4
(0.6 mmol), and the reaction mixture was stirred at room tempera-
ture for a selected time. The reaction progress was monitored by
TLC. After filtering and separation of the catalyst, the product was
extracted with diethyl ether and purified by column chromatogra-
phy. Product analysis was conducted by 1H NMR and 13C NMR spec-
troscopy and the identification of the products was carried out by
comparing the NMR spectra data with commercially available pure
substances.
[11] Q. H. Yang, Y. Z. Chen, Z. U. Wang, Q. Xu, H. L. Jiang, Chem. Commun.
2015, 51, 10419.
[12] K. S. Na, K. M. Choi, O. M. Yaghi, G. A. Somorjai, Nano Lett. 2014, 14,
5979.
[13] X. L. Liu, N. K. Demir, Z. T. Wu, K. Li, J. Am. Chem. Soc. 2015, 137, 6999.
[14] Z. D. Xu, L. Z. Yang, C. L. Xu, Anal. Chem. 2015, 87, 3438.
[15] W. Q. Zhou, B. H. Zou, W. N. Zhang, D. B. Tian, W. Huang, F. W. Huo,
Nanoscale 2015, 7, 8720.
[16] R. Wang, L. Gu, J. J. Zhou, X. Liu, F. Teng, C. Li, Y. Shen, Y. Yuan, Adv. Sci.
Adv. Mater. Interfaces 2015, 2, 1500037.
[17] M. Herrera-Alonso, A. A. Abdala, M. J. McAllister, I. A. Aksay, R. K.
Prud'homme, Langmuir 2007, 23, 10644.
[18] Y. X. Zhao, H. L. Ding, Q. Zhong, Appl. Surf. Sci. 2013, 284, 138.
[19] V. Zeleňák, Z. Vargová, M. Almáši, A. Zeleňáková, J. Kuchar, Microporous
Mesoporous Mater. 2010, 129, 354.
Acknowledgments
This work was supported by the Jiangsu Higher Education Insti-
tutions (Priority Academic Program Development, grant num-
ber 1281220030).
[20] H. Wang, T. Maiyalagan, X. Wang, ACS Catal. 2012, 2, 781.
[21] M. Kandiah, M. H. Nilsen, S. Usseglio, S. Jakobsen, U. Olsbye, M. Tilset, C.
Larabi, E. A. Quadrelli, F. Bonino, K. P. Lillerud, Chem. Mater. 2010, 22,
6632.
Keywords: Metal–organic frameworks · Nanoparticles ·
Palladium · Heterogeneous catalysis · Reduction
[22] M. Seredych, C. Petit, A. V. Tamashausky, T. J. Bandosz, Carbon 2009, 47,
445.
[1] S. Bhogeswararao, D. Srinivas, J. Catal. 2015, 327, 65.
[2] M. Martin-Martinez, L. M. Gómez-Sainero, J. Bedia, A. Arevalo-Bastante,
J. J. Rodriguez, Appl. Catal. B 2016, 184, 55.
[23] C. Petit, T. J. Bandosz, Adv. Funct. Mater. 2010, 20, 111.
[24] Z. G. Hu, Y. W. Peng, Z. Kang, Y. Qian, D. Zhao, Inorg. Chem. 2015, 54,
4862.
[25] L. Shi, T. Wang, H. Zhang, K. Chang, J. H. Ye, Adv. Funct. Mater. 2015, 25,
5360.
[26] S. Fountoulaki, V. Daikopoulou, P. L. Gkizis, I. Tamiolakis, G. S. Armatas,
I. N. Lykakis, ACS Catal. 2014, 4, 3504.
[3] S. H. Kim, H. Jeong, J. Kim, I. S. Lee, Small 2015, 11, 4884.
[4] T. Harada, S. Ikeda, Y. H. Ng, T. Sakata, H. Mori, T. Torimoto, M. Matsumura,
Adv. Funct. Mater. 2008, 18, 2190.
[5] C. Schäfer, S. C. Mhadgut, N. Kugyela, M. Török, B. Török, Catal. Sci. Tech-
nol. 2015, 5, 716.
[6] Z. B. Tian, Q. Y. Li, J. Y. Hou, L. Pei, Y. Li, S. Y. Ai, J. Catal. 2015, 331, 193.
[7] S. Horike, S. Shimomura, S. Kitagawa, Nature Chem. 2009, 1, 695.
Received: March 30, 2016
Published Online: ■
Eur. J. Inorg. Chem. 0000, 0–0
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