Bioorganic and Medicinal Chemistry p. 881 - 883 (1996)
Update date:2022-08-11
Topics:
Argade, Narshinha P.
Naik, Rajan H.
A simple and efficient synthesis of the ras farnesyl-protein transferase inhibitor chaetomellic acid A anhydride (1) is reported. The imidazopyridinium bromide S obtained from the reaction of 2-bromopalmitoyl chloride and 2-aminopyridine was reacted with maleic anhydride in the presence of NaOAc/AcOH to form 1 in 62% overall yield in three steps.
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