Carbohydrate Research p. 123 - 136 (1983)
Update date:2022-08-30
Topics:
Dill, Kilian
Daman, Marsha E.
Batstone-Cunningham, Ron L.
Lacombe, Jean M.
Pavia, Andre A.
Natural-abundance, 13C-n.m.r. spectroscopy was used to study the mode of binding of Gd(3+) to mono-O-glycosylated L-serine and tripeptides variously composed of Gly and L-Thr.When the amino and carboxyl groups of the amino acid are not blocked, strong interaction of Gd(3+) with them is observed; this is also readily apparent with some related, nonglycosylated peptides.When the amino and carboxyl and carboxyl groups of the amino acid are blocked, noticeble interaction of Gd(3+) with the glycosidic oxygen atom (O-3) and O-2' for the glycopeptide containing α-D-Galp, and with O-3 and N-2' for the glycopeptide containing α-D-GalpNAc, is observed.Weak interactions are also possible with O-4' and O-6' of the glycosyl groups.Although the amino acids were protected, these metal ion-carbohydrate interactions may still be mediated, to some extent, by the acetyl protecting the amino group and by the ester group on the amino acid.
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