Heterocycles p. 675 - 681 (2005)
Update date:2022-08-29
Topics:
Kumamoto, Koji
Iida, Hirokazu
Hamana, Hiroshi
Kotsuki, Hiyoshizo
Matsumoto, Kiyoshi
Employing double Strecker strategy, two new heterocyclic compounds, 5,6,11,12-tetrahydro-6,11-dimethyldibenzo[b,f][1,4]diazocine-6,11-dicarbonitrile and 1,2,3,4,5,10-hexahydrophenazine-4a, 10a-dicarbonitrile, were prepared in one step albeit in low yields. The reaction has proven to be very limited, but such a sterically hindered amine as N-methylaniline underwent Strecker reaction with benzaldehyde and TMSCN to give the corresponding α-amino nitriles.
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(2004)