Chemistry of Heterocyclic Compounds 2017, 53(6/7), 811–821
21. Matyjaszewski, K.; Müller, A. H. E. Controlled and Living
0.063 mol) and monomer BAMO (5b) (12.00 g, 0.071 mol)
was charged into a four-neck flask. The catalytic system
was prepared in a Schlenk vessel over 30 min by slow
addition of water (0.19 g, 0.011 mol) to TIBA (2.66 g,
0.013 mol) with continuous stirring under argon stream.
The catalytic system was gradually added under argon
stream to a continuously stirred mixture of monomers in
CH2Cl2 (10.0 ml), while maintaining the temperature at or
below 40°С by external cooling of the flask. The
polymerization reaction was continued for 10–20 h at 30–
40°С. The further isolation of the product was performed
according to the general method.
The copolymer was obtained in the form of a light-yellow,
thick resin with softening temperature of 54.1°С. ΔHf°
1775.0 kJ/kg. The characteristic viscosity was 0.50 dl/g.
Yield 18.2 g (91%). IR spectrum (thin film), ν, cm–1: 2107
(–N3), 1101 (C–O–C). Found, %: C 39.72; H 5.47;
N 41.87. C10H8.47N4.6O (unit). Calculated, %: C 40.32;
H 5.73; N 43.21.
Polymerizations: From Mechanisms to Applications; Willey-
VCH: Weinheim, 2009, p. 241.
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