Journal of Fluorine Chemistry p. 177 - 181 (1996)
Update date:2022-08-11
Topics:
Long, Zheng-Yu
Duan, Jian-Xin
Lin, Yuan-Bin
Guo, Cai-Yun
Chen, Qing-Yun
The trifluoromethylation of organic halides with FO2SCF2CF2OCF2CO2K (1) in DMF can be accomplished at 45 °C which is advantageous for thermally sensitive substrates. α-Carbon-oxygen bond fragmentation of 1 and the related β-carbon-oxygen bond scission are discussed.
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