Dalton Transactions p. 15075 - 15078 (2015)
Update date:2022-08-11
Topics:
Dutta, Ranjan
Akhuli, Bidyut
Ghosh, Pradyut
Encapsulation of hydrated sulfate in a bowl-shaped metal organic coordination polymer formed by Zn2+ assisted self-assembly of a 3-pyridyl terminated cyanuric acid platform based urea receptor is reported in aqueous medium. Trapping of an unusual [(SO4)4(H2O)12]8- cluster in a [Zn(H2O)6]2+ capped self-assembled structure is characterized by single crystal X-ray crystallography. Furthermore, selective binding of SO42- is established from the 1H-NMR titration study.
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