Chemistry - An Asian Journal
10.1002/asia.201800743
FULL PAPER
equipped with PHOTON II Detector (MoKα radiation, λ = 0.7107 Å),
controlled by the APEX3 (v2017.3-0) software package. Data collection
and data reduction were carried out using the software package APEX3
on a routine manner. The structure was solved by direct method and
[14] D. Díaz Díaz, D. Kühbeck, R. J. Koopmans, Chem. Soc. Rev. 2011, 40,
427–448.
[15] R. D. Mukhopadhyay, G. Das, A. Ajayaghosh, Nat. Commun. 2018, 9,
1–9.
2
refined by full-matrix least-squares based on F values against all
[16] S. Ghosh, V. K. Praveen, A. Ajayaghosh, Annu. Rev. Mater. Res. 2016,
46, 235–262.
reflections in SHELXL-2014 suite of APEX3. Final refinement and CIF
finalisation were carried out in OLEX2 version 1.2.8. The crystal structure
of CP6 was found to be merohedrally twin (refined twin component of
[17] A. Ajayaghosh, V. K. Praveen, C. Vijayakumar, Chem. Soc. Rev. 2008,
37, 109–122.
0
.288(5), 0.712(5)). All the nonhydrogen atoms were treated
[18] Y. R. Liu, L. He, J. Zhang, X. Wang, C. Y. Su, Chem. Mater. 2009, 21,
557–563.
anisotropically whereas most of the hydrogen atoms were geometrically
fixed; wherever possible, the hydrogen atoms associated with guest
solvents were located on difference Fourier map and refined. Ortep3
was used to generate the thermal ellipsoid plots. Final CIFs were
deposited to CCDC; CCDC no 1824071 (LP6) 1824068 (CP1) 1824065
[19] A. Döring, W. Birnbaum, D. Kuckling, Chem. Soc. Rev. 2013, 42, 7391-
7420.
[20] B. Escuder, F. Rodríguez-Llansola, J. F. Miravet, New J. Chem. 2010,
34, 1044-1224.
(
CP2) 1824070 (CP3) 1824067 (CP4) 1824066 (CP5) 1824069 (CP6).
These data can be obtained free of charge via
www.ccdc.cam.ac.uk/data_request/cif (or from Cambridge
[21] J.-S. Shen, Y.-L. Chen, J.-L. Huang, J.-D. Chen, C. Zhao, Y.-Q. Zheng,
T. Yu, Y. Yang, H.-W. Zhang, Soft Matter 2013, 9, 2017-2023.
[22] K. J. C. Van Bommel, A. Friggeri, S. Shinkai, Angew. Chem. Int. Ed.
2003, 42, 980–999.
the
[23] M.-O. M. Piepenbrock, N. Clarke, J. W. Steed, Soft Matter 2011, 7,
2
412-2418.
24] P. K. Vemula, U. Aslam, V. A. Mallia, G. John, Chem. Mater. 2007, 19,
38–140.
[
[
Powder X-ray diffraction
1
25] J. V. Herrikhuyzen, S. J. George, M. R. J. Vos, N. A. J. M. Sommerdijk,
A. Ajayaghosh, S. C. J. Meskers, A. P. H. J. Schenning, Angew. Chem.
Int. Ed. 2007, 46, 1825–1828.
PXRD data were collected using Bruker AXS D8 Advance powder
diffractometer (CuKα1 radiation, λ= 1.5406Å) equipped with super speed
LYNXEYE detector with a scan speed of 0.2 sec/step (step size=0.028
[
26] L. Zhu, X. Li, S. Wu, K. T. Nguyen, H. Yan, H. Ågren, Y. Zhao, J. Am.
Chem. Soc. 2013, 135, 9174–9180.
2) for the scan range of 2θ (5°–35°). The sample for data collection was
prepared by making a thin film of finely powdered sample (~20 mg) over
a glass slide.
[
[
27] B. O. Okesola, D. K. Smith, Chem. Commun. 2013, 49, 11164-11166.
28] J. Bachl, S. Oehm, J. Mayr, C. Cativiela, J. J. Marrero-Tellado, D. D.
Díaz, Int. J. Mol. Sci. 2015, 16, 11766–11784.
[
29] J. Majumder, P. Dastidar, Chem. Eur. J. 2016, 22, 9267–9276.
Acknowledgements
[30] D. R. Trivedi, P. Dastidar, Chem. Mater. 2006, 18, 1470–1478.
[
[
31] S. Bhattacharya, Y. K. Ghosh, Chem. Commun. 2001, 185–186.
32] E. Carretti, M. Bonini, L. Dei, B. H. Berrie, Accounts Chem. 2010, 43,
P. B. and S. G. thank Indian Association for the Cultivation of Science,
Kolkata for a research fellowship. PB also thanks Dr. Ahmed Hussain for
fruitful discussion in crystal structure refinement. P.D. thanks the
Department of Science & Technology, New Delhi, for financial support.
Single-crystal X-ray diffraction data were collected at the Department of
Biotechnology (DBT)-funded X-ray diffraction facility under the Centres of
Excellence and Innovation in Biotechnology (CEIB) program in the
Department of Organic Chemistry, IACS, Kolkata.
7
51–760.
33] E. Carretti, E. Fratini, D. Berti, L. Dei, P. Baglioni, Angew. Chem. Int. Ed.
009, 48, 8966–8969.
[
[
[
[
[
[
2
34] K. Murata, M. Aoki, T. Nishi, A. Ikeda, S. Shinkai, J. Chem. Soc. Chem.
Commun. 1991, 1715-1718.
35] B. L. Feringa, J. J. D. de Jong, L. N. Lucas, R. M. Kellogg, J. H. van
Esch, Science 2004, 304, 278–281.
36] K. K. Kartha, A. Sandeep, V. K. Praveen, A. Ajayaghosh, Chem. Rec.
2015, 15, 252–262.
Keywords: supramolecular gels; nanoparticles; coordination
37] A. R. Hirst, B. Escuder, J. F. Miravet, D. K. Smith, Angew. Chem. Int.
Ed. 2008, 47, 8002–8018.
polymers; crystal engineering; stimuli-responsive gels.
38] A. V. Kabanov, S. V. Vinogradov, Angew. Chem. Int. Ed. 2009, 48,
5418–5429.
[
[
[
[
1]
2]
3]
4]
P. Terech, R. G. Weiss, Chem. Rev. 1997, 97, 3133–3160.
R. G. Weiss, J. Am. Chem. Soc. 2014, 136, 7519–7530.
D. K. Smith, Nat. Chem. 2010, 2, 162–163.
[39] F. Zhao, M. L. Ma, B. Xu, Chem. Soc. Rev. 2009, 38, 883-891.
[40] J. Majumder, J. Deb, M. R. Das, S. S. Jana, P. Dastidar, Chem.
Commun. 2014, 50, 1671-1674.
E. R. Draper, D. J. Adams, Chem. Soc. Rev. 2018, DOI
1
0.1039/C7CS00804J.
F. M. Menger, K. L. Caran, J. Am. Chem. Soc. 2000, 122, 11679–
1691.
[41] K. Y. Lee, M. C. Peters, K. W. Anderson, D. J. Mooney, Nature 2000,
408, 998–1000.
[
5]
1
[42] K. Y. Lee, D. J. Mooney, Chem. Rev. 2001, 101, 1869–1879.
[43] B. Xing, M.-F. Choi, B. Xu, Chem. Commun. 2002, 362–363.
[44] A. Y.-Y. Tam, V. W.-W. Yam, Chem. Soc. Rev. 2013, 42, 1540-1567.
[45] T. Feldner, M. Häring, S. Saha, J. Esquena, R. Banerjee, D. D. Díaz,
Chem. Mater. 2016, 28, 3210–3217.
[
[
[
[
6]
7]
8]
9]
J. H. Jung, M. Park, S. Shinkai, Chem. Soc. Rev. 2010, 39, 4286-4302.
P. Dastidar, Chem. Soc. Rev. 2008, 37, 2699-2715.
M. Suzuki, K. Hanabusa, Chem. Soc. Rev. 2009, 38, 967-975.
S. S. Babu, V. K. Praveen, A. Ajayaghosh, Chem. Rev. 2014, 114,
1
973–2129.
[46] K. Hanabusa, Y. Maesaka, M. Suzuki, M. Kimura, H. Shirai, Chem. Lett.
2000, 29, 1168–1169.
[
[
10] J. W. Steed, Chem. Soc. Rev. 2010, 39, 3686-3699.
11] M. D. Segarra-Maset, V. J. Nebot, J. F. Miravet, B. Escuder, Chem.
Soc. Rev. 2013, 42, 7086–7098.
[47] D. López, J. M. Guenet, Macromolecules 2001, 34, 1076–1081.
[48] T. Ishi- i, R. Iguchi, E. Snip, M. Ikeda, S. Shinkai, Langmuir 2001, 17,
5825–5833.
[
[
12] J. H. Van Esch, B. L. Feringa, Angew. Chem. Int. Ed. 2000, 39, 2263–
2266.
[49] M. Kimura, T. Muto, H. Takimoto, K. Wada, K. Ohta, K. Hanabusa, H.
Shirai, N. Kobayashi, Langmuir 2000, 16, 2078–2082.
13] K. N. King, A. J. McNeil, Chem. Commun. 2010, 46, 3511-3513.
This article is protected by copyright. All rights reserved.