Tetrahedron Letters p. 8937 - 8940 (1995)
Update date:2022-08-17
Topics:
Thompson, Andrew S.
Corley, Edward G.
Huntington, Martha F.
Grabowski, E. J. J.
The asymmetric synthesis of L-743,726 was achieved in six steps with an overall yield of 31 percent.The asymmetry was introduced using a lithiated ephedrine to mediate acetylide addition to a trifluoromethyl ketone with an enantiomeric excess of 96-98 percent.
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