Tetrahedron Letters p. 7507 - 7511 (1999)
Update date:2022-08-11
Topics:
Iwasaki, Fumiaki
Onomura, Osamu
Mishima, Katsuhiko
Maki, Toshihide
Matsumura, Yoshihiro
Some kinds of N-formyl cyclic amine derivatives were found to be effective activators for trichlorosilane to reduce ketones. Namely, a catalytic amount of these activators were sufficient to complete the reduction of ketones with trichlorosilane, and the reduction of ketones by trichlorosilane with optically active activators gave enantiomerically enriched sec-alcohols in some extent of optical yields (up to 51% ee).
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