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Green Chemistry
Page 6 of 8
DOI: 10.1039/C6GC03141B
ARTICLE
Journal Name
Commun., 2014,
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In summary, the inexpensive and highly stable non-noble Ni-
MoO3/CN@SBA-15 catalysts have been prepared by treating
SBA-15-supported nickel-molybdenum oxide materials with
1,10-phenanthroline. The catalysts highly efficiently and
quantitatively reduce various functionalized nitroarenes to the
corresponding aniline in > 99% yields with hydrazine hydrate
due to the synergistic effect of metal Ni and MoO3 species. The
recycling tests and characterizations demonstrated that the Ni-
6.%MoO3/CN@SBA-15 is highly stable and can be reused for
the reduction of nitroarenes. This work can spur much interest
in developing novel non-noble catalysts for other important
reduction reactions.
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Boronat, P. Concepción, A. Corma, S. González, F. Illas and P.
This research was supported by Innovation Program of
Shanghai Municipal Education Commission (14ZZ100),
Independent Research and Development Project of State Key
Laboratory of Advanced Special Steel of Shanghai University,
the Major State Basic Research Development Program of China
(No. 2014CB643403), National Science Fund for Distinguished
Young Scholars (No. 51225401, 51574164) and Basic Major
Research Program of Science, and Technology Commission
Foundation of Shanghai (No. 14JC1491400).
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