Bulletin of the Chemical Society of Japan p. 1393 - 1398 (1980)
Update date:2022-08-30
Topics:
Kitamura, Akihide
Sakuragi, Hirochika
Yoshida, Masayuki
Tokumaru, Katsumi
Attempts have been made to elucidate the mechanism for the efficient production of phenyl benzoate, the geminate product, from direct and singlet sensitized irradiations of dibenzoyl peroxide in solution.It is concluded that these irradiations produce a reactive state of the peroxide which can undergo two-bond cleavage of the O-O and C(α)-C(carbonyl) bonds to give a phenyl-benzoyloxy radical pair in a solvent cage, followed by the recombination of the component radicals to give the geminate product or by their diffusion out of the solvent cage to give diffusion products.
View MoreLonghui qunfeng Chemical Co., Ltd
Contact:86-731-82173407
Address:South-east Industrial Park, Longhui County, Hunan Province, China
Beijing Stable Chemcial Co.ltd
Contact:86-10-63785052
Address:A1301 Technological Edifice. No.4 FuFeng Road,FengTai District, Beijing. China
NanJing Rate Biochemicals CO., LTD
Contact:+86-25-84931986
Address:NO. 1 Hongjing Road,Jiangning Science Park,Nanjing,China
Contact:+86-21-54391580
Address:Room 502,No.65,Lane 2388 Hongxin Road,Shanghai,China
Shandong Loyal Chemical industrial Co.,Ltd
Contact:0533-7451788
Address:Linzi Chemical Industrial Park, Zibo, Shandong Province
Doi:10.1016/S0022-1139(00)82102-8
(1976)Doi:10.1002/(SICI)1096-9888(199807)33:7<631::AID-JMS668>3.0.CO;2-M
(1998)Doi:10.1246/bcsj.61.2244
(1988)Doi:10.1021/jacs.5b01599
(2015)Doi:10.1021/cg5010165
(2014)Doi:10.1007/BF00962295
(1987)