Tetrahedron Asymmetry p. 867 - 870 (1991)
Update date:2022-08-16
Topics:
Hamdani
De Jeso
Deleuze
Maillard
Baker's yeast reduction of ethyl acetoacetate provided in good yield ethyl 2(S)-hydroxybutanoate. The hydrolysis of the ester function after protection of the hydroxyl yielded an acid which, under BARTON'S free radical decarboxylation conditions, produced a free radical chiron of 2(S)-hydroxypropyl moiety; according to the reaction medium various chiral products from reaction of this entity were produced.
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