Chemistry Letters p. 1345 - 1348 (1994)
Update date:2022-08-11
Topics:
Fujibayashi, Shinya
Nakayama, Kouichi
Nishiyama, Yutaka
Ishii, Yasutaka
Vanadomolybdophosphate supported on active carbon, NPV6Mo6/C, catalyzed the oxidation and coupling reaction of 2,3,6-trimethylphenol by dioxygen to give trimethyl-p-benzoquinone and 4,4'-dihydroxy-2,2',3,3',5,5'-hexamethylbiphenyl, respectively, depending on the solvent used.Hydroquinones and benzyl alcohol were selectively dehydrogenated by the present system, giving the corresponding p-benzoquinones and benzaldehyde, respectively, in good yields.
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