Chemistry Letters p. 993 - 996 (1985)
Update date:2022-08-23
Topics:
Matsuura, Akira
Nishinaga, Akira
Ito, Yoshikatsu
Matsuura, Teruo
9-t-butyl-10-methyl-9,10-endotrioxy-9,10-dihydroanthracene underwent reductive decomposition readily with transition metal compounds having one-electron reducibility to result unexpectedly in the specific cleavage of the shorter O-O bond close to the t-butyl group in the trioxide finally giving rise to 10-methyloxanthrone and t-butyl alcohol.A plausible mechanism is discussed.
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