Russian Chemical Bulletin p. 863 - 865 (1993)
Update date:2022-08-11
Topics:
Zakharkin, L. I.
Churilova, I. M.
Petrovskii, P. V.
The composition of the products obtained in the reaction of n-BuMgBr and n-BuLi with cyclododecanone (1) has revealed that 1 exhibits the properties of a sterically hindered ketone.The highest yield of 1-butylcyclododecanol (2) was achieved with the use of n-BuMgBr, but in this case cyclododecanol was also formed, whereas the use of n-BuLi led to the tertiary alcohol more distinctly.Dehydration of alcohol 2 resulted in a mixture of three olefins containing up to 90percent of E- and Z- isomers of 1-butylcyclododecene.
View MoreWUXI KINGHAN BIO-MEDICAL&CHEMICAL INC.
Contact:13861062998
Address:Room 1316,No.1619 Huishan Avenue,Wuxi,China
Shanghai Balmxy Pharmaceutical Co., Ltd
Contact:0086-21-24206007
Address:Room 402, 15#, No. 909 wangyue Road, shanghai, P. R. China
BAODING SINO-CHEM INDUSTRY CO.,LTD
Contact:0312-5956088
Address:NO.8 FUXING ROAD,CHINA
Hangzhou Pharma & Chem Co.,Ltd.
Contact:+86-571-87040515
Address:No,139Qingchun Rd
Contact:+86-10-67147360/67107388
Address:No.18 Guangming Zhongjie, Chongwen District, Beijing, 100061, China
Doi:10.1016/j.tetlet.2016.05.102
(2016)Doi:10.1021/jo00361a038
(1986)Doi:10.1016/S0040-4039(98)02464-2
(1999)Doi:10.1002/jhet.5570210530
(1984)Doi:10.1080/00958972.2020.1771558
(2020)Doi:10.1039/b614427f
(2007)