Journal of the Chemical Society. Chemical communications p. 171 - 172 (1985)
Update date:2022-08-10
Topics:
Belokon', Yuri N.
Chernoglazova, Nina I.
Kochetkov, Constantin A.
Garbalinskaya, Natalia S.
Belikov, Vasili M.
Chiral nickel(II) complexes of Ala with (S)-2-N-(N'-benzylprolyl)aminobenzaldehyde <(S)-bba> were alkylated with alkyl halides and the diastereoisomeric complexes formed were separated on SiO2; their decomposition led to the isolation of enantiomerically pure (R)- and (S)-α-alkyl-α-amino acids with recovery of the initial (S)-bba.
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