Tetrahedron Asymmetry p. 1027 - 1032 (1996)
Update date:2022-08-11
Topics:
Chelucci, Giorgio
Cabras, M. Antonietta
Saba, Antonio
Sechi, Alessandra
The synthesis and resolution of 1,1-bi-8-methylisoquinoline (±)-5 is reported. An optically active palladium complex with high chiral recognition was formed during the complexation between a chiral palladium complex and the two enantiomers of (±)-5. The free energy barrier ΔGF(≠) for interconversion of enantiomers was estimated to be 97,2 KJ/mol at 40°C.
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