Journal of Organometallic Chemistry p. 217 - 226 (1981)
Update date:2022-08-11
Topics:
Schumann, H.
Frank, U.
Mont, W. W. du
Marschner, F.
Di-t-butylchloroarsine reacts with t-butyllithium to give tri-t-butylarsine and with trimethylchlorosilane-magnesium-tetrahydrofuran under formation of di-t-butyl(trimethylsilyl)arsine.Tris(trimethylsilyl)arsine was obtained in a similar way from arsenic trichloride with trimethylchlorosilane-magnesium-HMPA.Trimethylsilylarsines react with trimethylchloro-germane and -stannane to give the corresponding trimethyl-germyl- and stannyl-arsines.Organometalarsines react with hexacarbonyl-chromium, -molybdenum, or -tungsten with formation of pentacarbonyl(organometalarsine)- chromium, -molybdenum, or -tungsten complexes.NMR, IR, Raman, and He(I)-PE data of the new bulky arsine ligands and of some complexes are reported.
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