Journal of Organometallic Chemistry p. 19 - 30 (1989)
Update date:2022-08-11
Topics:
Blankenship, Craig
Cremer, Sheldon E.
Cesium fluoride isomerization of several derivatives of 3-silabicyclo<3.2.1>octane and 2-silabicyclo<2.2.1>heptane as well as chiral α-NpPhMeSiH are described.The effect of solvent, 18-crown-6 ether, and other salts is discussed.Associated side reactions prompted study of the conversion of Ph3SiH to Ph3SiF by CsF and the identification of the products formed from the reaction of Ph3SiH with DMF, N-methylformanilide, and benzamide in the presence of metal fluorides.
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