Crystal Growth & Design
Communication
(25) Xu, L.; Wang, Y. X.; Yang, H. B. Recent Advances in the
construction of fluorescent metallacycles and metallocages via
coordination-driven assembly. Dalton Trans 2015, 44, 867−890.
(26) Guzman-Percastegui, E.; Vonlanthen, M.; Quiroz-Garcia, B.;
Flores-Alamo, M.; Rivera, E.; Castillo, I. Supramolecular Fluorescence
Enhancement via Coordination Driven Self-Assembly in Rigid bis-
Picolylcalixarene-derived Blue Emitting M2L2Xn Macrocycles. Dalton
Trans. 2015, 44, 15966−15975.
Blocks: Syntheses, Structures, and Heterogeneous Catalysis. Inorg.
Chem. 2013, 52, 10773−10787.
(46) Kumar, G.; Kumar, G.; Gupta, R. Lanthanide-based
coordination polymers as promising heterogeneous catalysts for
ring-opening reactions. RSC Adv. 2016, 6, 21352−21361.
(47) Kumar, G.; Gupta, R. Cobalt Complexes Appended with p- and
m-Carboxylates: Two Unique {Co3+−Cd2+} Networks and Their
Regioselective and Size-Selective Heterogeneous Catalysis. Inorg.
Chem. 2012, 51, 5497−5499.
(27) Webber, M. J.; Langer, R. Drug delivery by supramolecular
design. Chem. Soc. Rev. 2017, 46, 6600−6620.
(48) Samanta, D.; Mukherjee, S.; Patil, Y. P.; Mukherjee, P. S. Self-
Assembled Pd6 Open Cage with Triimidazole Walls and the Use of Its
Confined Nanospace for Catalytic Knoevenagel- and Diels−Alder
Reactions in Aqueous Medium. Chem.−Eur. J. 2012, 18, 12322−
12329.
(49) Srivastava, S.; Dagur, M. S.; Ali, A.; Gupta, R. Trinuclear {Co
2+−M3+−Co2+} complexes catalyze reduction of nitro compounds.
Dalton Trans 2015, 44, 17453−17461.
(50) Pandey, S.; Kumar, G.; Gupta, R. Postfunctionalized Metal-
loligand-Based Catenated Coordination Polymers: Syntheses, Struc-
tures, and Effect of Labile Sites on Catalysis. Cryst. Growth Des. 2019,
19, 2723−2735.
(28) Ma, D.; Hettiarachchi, G.; Nguyen, D.; Zhang, B.; Wittenberg,
J. B.; Zavalij, P. Y.; Briken, V.; Isaacs, L. Acyclic cucurbit[n]uril
molecular containers enhance the solubility and bioactivity of poorly
soluble pharmaceuticals. Nat. Chem. 2012, 4, 503−510.
(29) Plumb, J. A.; Venugopal, B.; Oun, R.; Gomez-Roman, N.;
Kawazoe, Y.; Venkataramanan, N. S.; Wheate, N. J. Cucurbit[7]uril
encapsulated cisplatin overcomes cisplatin resistance via a pharmaco-
kinetic effect. Metallomics 2012, 4, 561−567.
̀
(30) Mejia-Ariza, R.; Grana-Suarez, L.; Verboom, W.; Huskens, J.
Cyclodextrin-based supramolecular nanoparticles for biomedical
applications. J. Mater. Chem. B 2017, 5, 36−52.
(51) Mishra, A.; Ali, A.; Upreti, S.; Gupta, R. Cobalt Coordination
Induced Functionalized Molecular Clefts: Isolation of {CoIII-Zn-II}
Heterometallic Complexes and Their Applications in Beckmann
Rearrangement Reactions. Inorg. Chem. 2008, 47, 154−161.
(52) Bansal, D.; Pandey, S.; Hundal, G.; Gupta, R. Heterometallic
coordination polymers: syntheses, structures and heterogeneous
catalytic applications. New J. Chem. 2015, 39, 9772−9781.
(53) Mishra, A.; Ali, A.; Upreti, S.; Whittingham, M. S.; Gupta, R.
Cobalt complex as building blocks: synthesis, characterization, and
catalytic applications of {Cd2+-Co3+-Cd2+} and {Hg2+-Co3+-Hg2+}
heterobimetallic complexes. Inorg. Chem. 2009, 48, 5234−5243.
(54) Stang, P. J.; Olenyuk, B. Self-Assembly, Symmetry, and
Molecular Architecture: Coordination as the Motif in the Rational
Design of Supramolecular Metallacyclic Polygons and Polyhedra. Acc.
Chem. Res. 1997, 30, 502−518.
(31) Duan, Q.; Cao, Y.; Li, Y.; Hu, X.; Xiao, T.; Lin, C.; Pan, Y.;
Wang, L. pH-Responsive Supramolecular Vesicles Based on Water-
Soluble Pillar[6]arene and Ferrocene Derivative for Drug Delivery. J.
Am. Chem. Soc. 2013, 135, 10542−10549.
(32) Loh, X. J. Supramolecular host−guest polymeric materials for
biomedical applications. Mater. Horiz. 2014, 1, 185−195.
(33) Giuliani, M.; Morbioli, I.; Sansone, F.; Casnati, A. Moulding
calixarenes for biomacromolecule targeting. Chem. Commun. 2015, 51,
14140−14159.
(34) Rajora, M. A.; Lou, J. W. H.; Zheng, G. Advancing porphyrin’s
biomedical utility via supramolecular chemistry. Chem. Soc. Rev. 2017,
46, 6433−6469.
́ ́
(35) Gandara-Loe, J.; Ortuno-Lizaran, I.; Fernandez-Sanchez, L.;
̃
́
Alio, J. L.; Cuenca, N.; Vega-Estrada, A.; Silvestre-Albero, J. Metal−
Organic Frameworks as Drug Delivery Platforms for Ocular
Therapeutics. ACS Appl. Mater. Interfaces 2019, 11, 1924−1931.
(36) Marsault, E.; Peterson, M. L. Macrocycles Are Great Cycles:
Applications, Opportunities, and Challenges of Synthetic Macrocycles
in Drug Discovery. J. Med. Chem. 2011, 54, 1961−2004.
(55) Yoshizawa, M.; Klosterman, J. K.; Fujita, M. Functional
Molecular Flasks: New Properties and Reactions within Discrete, Self-
Assembled. Angew. Chem., Int. Ed. 2009, 48, 3418−3438.
(56) Fujita, M.; Tominaga, M.; Hori, A.; Therrien, B. Coordination
Assemblies from a Pd(II)-Cornered Square Complex. Acc. Chem. Res.
2005, 38, 369−378.
(37) Galan, A.; Ballester, P. Stabilization of reactive species by
supramolecular encapsulation. Chem. Soc. Rev. 2016, 45, 1720−1737.
(38) Fiedler, D.; Bergman, R. G.; Raymond, K. N. Stabalization of
Reactive Organometallic Inetermediates inside a Self Assembled
Nanoscale Host. Angew. Chem., Int. Ed. 2006, 45, 745−748.
(39) Eelkema, R.; Maeda, K.; Odell, B.; Anderson, H. L. Radical
Cation Stabilization in a Cucurbituril Oligoaniline Rotaxane. J. Am.
Chem. Soc. 2007, 129, 12384−12385.
̈
(57) Olenyuk, B.; Fechtenkotter, A.; Stang, P. J. Molecular
architecture of cyclic nanostructures: use of co-ordination chemistry
in the building of supermolecules with predefined geometric shapes. J.
Chem. Soc., Dalton Trans. 1998, 1707−1728.
(58) Chakrabarty, R.; Mukherjee, P. S.; Stang, P. J. Supramolecular
Coordination: Self-Assembly of Finite Two- and Three-Dimensional
Ensembles. Chem. Rev. 2011, 111, 6810−6918.
(40) Pandey, S.; Bansal, D.; Gupta, R. A Metalloligand Appended
(59) Tong, J.; Jia, L. M.; Shang, P.; Yu, S. Y. Controlled Synthesis of
Supramolecular Architectures of Homo- and Heterometallic Com-
plexes by Programmable Self-Assembly. Cryst. Growth Des. 2019, 19,
30−39.
with Benzimidazole Rings: Tetranuclear [CoZn3 ] and [CoCd3
]
Complexes and Their Catalytic Applications. New J. Chem. 2018, 42,
9847−9856.
(41) Liu, Y.; Zhang, R.; He, C.; Dang, D.; Duan, C. A palladium(II)
triangle as building blocks of microporous molecular materials:
structures and catalytic performance. Chem. Commun. 2010, 46, 746−
748.
(42) Srivastava, S.; Kumar, V.; Gupta, R. A Carboxylate-Rich
Metalloligand and Its Heterometallic Coordination Polymers: Syn-
thesis, Structures, Topologies and Heterogeneous Catalysis. Cryst.
Growth Des. 2016, 16, 2874−2886.
(43) Kumar, G.; Hussain, F.; Gupta, R. Carbon-sulphur cross
coupling reactions catalyzed by nickel-based coordination polymers
based on metalloligands. Dalton Trans 2017, 46, 15023−15031.
(44) Kumar, G.; Kumar, G.; Gupta, R. Manganese and Cobalt-Based
Coordination Networks as Promising Heterogeneous Catalysts for
Olefin Epoxidation Reactions. Inorg. Chem. 2015, 54, 2603−2615.
(45) Kumar, G.; Gupta, R. Three-Dimensional {Co3+−Zn2+} and
{Co3+− Cd2+} Networks Originated from Carboxylate-rich Building
(60) Caulder, D. L.; Raymond, K. N. Supermolecules by Design. Acc.
Chem. Res. 1999, 32, 975−982.
(61) Burchell, T. J.; Eisler, D. J.; Puddephatt, R. J. Self-Assembly
Using Dynamic Coordination Chemistry and Hydrogen Bonding:
Mercury(II) Macrocycles, Polymers and Sheets. Inorg. Chem. 2004,
43, 5550−5557.
(62) Nasser, N.; Borecki, A.; Boyle, P. D.; Puddephatt, R. J. A
Versatile Diphosphine Ligand: cis and trans Chelation or Bridging,
with Self Association through Hydrogen Bonding. Inorg. Chem. 2013,
52, 7051−7060.
(63) Marshall, L. J.; de Mendoza, J. Self-Assembled Squares and
Triangles by Simultaneous Hydrogen Bonding and Metal Coordina-
tion. Org. Lett. 2013, 15, 1548−1551.
(64) Casnati, A.; Sansone, F.; Ungaro, R. Peptido- and
Glycocalixarenes: Playing with Hydrogen Bonds around Hydrophobic
Cavities. Acc. Chem. Res. 2003, 36, 246−254.
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