Heterocycles p. 835 - 842 (2007)
Update date:2022-08-18
Topics:
Akiyama, Taiji
Hirao, Atsuko
Okujima, Tetsuo
Yamada, Hiroko
Uno, Hidemitsu
Ono, Noboru
Mg complex of phthalocyanine fused with bicyclo[2.2.2]octadiene (BCOD) units is prepared by the reaction of BCOD-fused phthalonitrile with Mg(OPr)2 in PrOH at 100 °C overnight in 42% yield. Subsequent heating the product at 250 °C results in clean formation naphthalocyanine via the retro Diels-Alder reaction. An attempt to the synthesis of BCOD-fused tetraazaporphyrin by the similar cyclization of the Diels-Alder adduct of dicyanoacetylene with 1,3-cyclohexadiene was unsuccessful.
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Doi:10.1002/zaac.201200394
(2013)Doi:10.1016/j.ejmech.2015.10.055
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(2021)Doi:10.1039/c7ra13776a
(2018)Doi:10.1021/jo972339i
(1998)