Inorganic Chemistry p. 8081 - 8098 (2020)
Update date:2022-08-18
Topics:
Bai, Feng-Ying
Guan, Qing-Lin
Liu, Chun-Hong
Sun, Li-Xian
Xing, Yong-Heng
Yang, Xiao-Dong
Four new complexes, [Zn(TIBTC)(DMA)]·[NH2(CH3)2] (1), [Cd(TIBTC)(H2O)]·[NH2(CH3)2]·DMA (2), [Cd2(TIBTC)(2,2′-bipy)2(HCOO)] (3), and [Cd2(DIBTC)(2,2′-bipy)2(HCOO)] (4) (H3TIBTC = 2,4,6-triiodo-1,3,5-benzenetricarboxylic acid, H3DIBTC = 2,4-diiodo-1,3,5-benzenetricarboxylic acid, 2,2′-bipy = 2,2′-bipyridine, and DMA = dimethylacetamide), were successfully synthesized and characterized by elemental analysis, powder X-ray diffraction, infrared spectroscopy, ultraviolet-visible spectroscopy, and thermogravimetric analysis. Complexes 1 and 2 are three-dimensional supramolecular network structures, while complex 4 has a two-dimensional network structure. We preliminarily studied the fluorescence properties of the complexes and found that complexes 1-3 can detect thiamine hydrochloride, NACs, and Fe3+/Zn2+ with high sensitivity and selectivity.
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