Tetrahedron Letters p. 4183 - 4186 (1997)
Update date:2022-08-11
Topics:
Paterson, Ian
McLeod, Malcolm D.
The C1-C13 segment 6 of concanamycin A (1) was prepared by a highly stereocontrolled route (87% overall ds) in 16 steps from the ester 9. Key steps are the one-pot aldol/reduction, 8 → 12, and the HWE reaction, 18 + 19 → 6.
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