Journal of the American Chemical Society
Communication
ring size of the TMC ligand has a significant effect not only on the
Lim, M. H.; Hedman, B.; Hodgson, K. O.; Valentine, J. S.; Solomon, E.
I.; Nam, W. Nature 2011, 478, 502.
determination of metal-O structures but also on the reactivity of
2
(10) (a) Kieber-Emmons, M. T.; Annaraj, J.; Seo, M. S.; Van Heuvelen,
the resulting metal-oxo complexes toward NO and NO2.
K. M.; Tosha, T.; Kitagawa, T.; Brunold, T. C.; Nam, W.; Riordan, C. G.
J. Am. Chem. Soc. 2006, 128, 14230. (b) Cho, J.; Sarangi, R.; Annaraj, J.;
Kim, S. Y.; Kubo, M.; Ogura, T.; Solomon, E. I.; Nam, W. Nature Chem.
ASSOCIATED CONTENT
Supporting Information
■
*
S
2
009, 1, 568.
Experimental details, purification of NO, trapping experiments,
(11) (a) Cho, J.; Woo, J.; Nam, W. J. Am. Chem. Soc. 2010, 132, 5958.
(b) Cho, J.; Woo, J.; Nam, W. J. Am. Chem. Soc. 2012, 134, 11112.
(12) Yokoyama, A.; Han, J. E.; Cho, J.; Kubo, M.; Ogura, T.; Siegler, M.
A.; Karlin, K. D.; Nam, W. J. Am. Chem. Soc. 2012, 134, 15269.
(13) Abbreviations used: 12-TMC, 1,4,7,10-tetramethyl-1,4,7,10-
tetraazacyclododecane; 14-TMC, 1,4,8,11-tetramethyl-1,4,8,11-tetraa-
zacyclotetradecane.
AUTHOR INFORMATION
Notes
(14) A NO-saturated solution was prepared under 1 atm at 298 K; the
concentration of the NO in CH CN at 293 K was approximated to be 14
3
mM. For the published values for NO solubilities in organic solvents,
see: Young, C. L Oxides of Nitrogen; Solubility Data Series Vol. 8;
International Union of Pure and Applied Chemistry: 1981. The
purification of NO is described in the SI (experimental section and
Figure S1).
The authors declare no competing financial interest.
ACKNOWLEDGMENTS
■
(15) (a) Hempel, J. C.; Morgan, L. O.; Lewis, W. B. Inorg. Chem. 1970,
The authors gratefully acknowledge research support of this
work by the NRF of Korea through CRI (2-2012-1794-001-1 to
W.N.) and GRL (2010-00353 to W.N.) and the U.S. National
Institutes of Health (K.D.K.).
9, 2064. (b) Ueki, S.; Yamauchi, J. Inorg. Chim. Acta 2002, 338, 13.
III
(16) Characterization of the Cr -PN species 2 with ESI-MS in this
case was unsuccessful due to its thermal instability. We note that there is
no example of resonance Raman spectroscopic characterization of a
metal-peroxynitrite complex, probably due to photodecay of the
intermediate during measurements: Tran, N. G.; Kalyvas, H.; Skodje,
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