Synthetic Communications p. 481 - 487 (1991)
Update date:2022-08-23
Topics:
Ikoma
Ando
Naoi
Akiyama
Sugimori
The reactions of aryl Grignard reagents with p- and m-bromochlorobenzenes catalyzed by non-ligated NiCl2 give selectively chlorobiphenyl derivatives. By the stepwise reaction, an unsymmetrical terphenyl was synthesized in a good yield.
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