1
950
C. Pugh et al.
LETTER
Hz). 13C NMR (75 MHz, CDCl ): d = 40.4 (CHBr), 53.5 (CH ), 64.6
(14) (a) Müller, A. H. E.; Yan, D.; Wulkow, M. Macromolecules
1997, 30, 7015. (b) Yan, D.; Müller, A. H. E.;
3
3
(
CH O C), 127.6 (CH=), 132.4 (CH =), 165.3 (acrylate C=O),
2
2
2
1
68.3 (CO CH ). Anal. Calcd: C 35.47; H, 3.83. Found: C, 35.24;
Matyjaszewski, K. Macromolecules 1997, 30, 7024.
(15) For example: (a) Matyjaszewski, K.; Gaynor, S. G.; Kulfan,
A.; Podwika, M. Macromolecules 1997, 30, 5192.
2
3
H, 3.75.
(
3
b) Matyjaszewski, K.; Gaynor, S. G. Macromolecules 1997,
0, 7042. (c) Matyjaszewski, K.; Pyun, J.; Gaynor, S. G.
Supporting Information for this article is available online at
http://www.thieme-connect.com/ejournals/toc/synlett. Included are
additional experimental details, all remaining synthetic procedures,
polymerization and copolymerization procedures and NMR spectra.
Macromol. Rapid Commun. 1998, 19, 665. (d) Yoo, S. H.;
Yoon, T. H.; Jho, J. Y. Macromol. Rapid Commun. 2001, 22,
1
319. (e) Ishizu, K.; Shibuya, T.; Mori, A. Polym. Int. 2002,
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Macromolecules 2002, 35, 1146. (g) Hong, C. Y.; You, Y.
Z.; Wu, D.; Liu, Y.; Pan, C. Y. Macromolecules 2005, 38,
Acknowledgment
2
606.
We acknowledge the National Science Foundation for support of
this research through DMR-0322338 and its Special Creativity
Award (DMR-0630301). We also gratefully acknowledge the Ohio
Board of Regents for a matching award.
(
(
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