Journal of Physical Chemistry p. 1900 - 1905 (1987)
Update date:2022-08-11
Topics:
Higashihara, T.
Gardiner, W. C.
Hwang, S. M.
The thermal decomposition of CH3NH2 was studied by IR laser kinetic absorption spectroscopy behind reflected shock waves with 1400 < T5 < 1820 K and 4.0E-6 < ρ5 < 8.0E-6 mol cm-3.The absorption profiles were satisfactorily modeled with a 28-reaction mechanism based on earlier investigations.The initial decomposition was found to be dominated by CH3NH2 + M -> CH3 + NH2 + M (ΔHo0 = 350 kJ) under these conditions, for which the rate constant expression ka = 5E17 exp(-260kJ/RT) cm3 mol-1 s-1 was derived.
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