Heterocycles p. 481 - 489 (1998)
Update date:2022-08-11
Topics:
Wang, Eng Chi
Lin, Huey-Jen
γ- and δ-Chloroalkanamides were found to undergo lactamization readily when treated with potassium tert-butoxide in tetrahydrofuran. Raising the reaction temperature may encourage SN2 displacement reaction. On the other hand β-chloroalkanamides only undergo elimination, followed by dimerization and trimerization of the acrylamide initially formed.
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