Tetrahedron p. 9765 - 9784 (1998)
Update date:2022-08-11
Topics:
Banks, Malcolm R.
Cadogan
Gosney, Ian
Gould, Robert O.
Hodgson, Philip K. G.
McDougall, Douglas
A newly developed fructose-based homochiral 1,3-oxazin-2-one reagent prepared via a regioselective and stereoselective intramolecular nitrene insertion reaction (INIR) exerts smooth stereocontrol resulting in high levels of asymmetric induction and chemical yield in various synthetic transformations including aldol, Diels-Alder cycloaddition and α-bromination reactions.
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