Organic and Biomolecular Chemistry p. 9035 - 9038 (2020)
Update date:2022-08-16
Topics:
Chen, Shanchong
Chen, Yuchan
Dong, Chunmao
Liu, Hongxin
Liu, Zhaoming
Tan, Haibo
Zhang, Weimin
Zhang, Xiao
A highly substituted phenol derivative, effphenol A (1), was isolated from the deep-sea-derived fungus Trichobotrys effuse FS524. Its complete structural assignment was established through a combination of spectroscopic analysis together with single-crystal X-ray diffraction experiments and further unequivocally confirmed by a biomimetic total synthesis. Structurally, effphenol A possesses a poly-substituted 6-5/6/6 tetracyclic ring system, which represents the first case of such a skeleton found in nature. Furthermore, the cytotoxic activity of effphenol A (1) toward four human cancer cell lines was assayed. This journal is
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