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This research was supported by a Grant-in-Aid for Scientific
Research from the Japan Society for the Promotion of Science
(Nos. 26410114 and 15H03808). The authors are grateful to Dr.
K. Oyama (Nagoya University) for technical support with mass
spectrometry measurements.
Keywords: asymmetric synthesis • alkynylation • ketone •
rhodium • pincer ligand
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