Helvetica Chimica Acta p. 59 - 62 (1987)
Update date:2022-08-10
Topics:
Klaic, Branimir
Raza, Zlata
Sankovic, Mauricio
Sunjic, Vitomir
Heptamolybdate-ion(HM)-catalyzed C(2) epimerization of D-glucose and racemization of D-glyceraldehyde proceed with comparable rates and activation parameters; HM catalyzes the isomerisation of glucal and galactal triacetates as well.For all of the above transformations, a common, new mechanism is proposed that invokes stabilization of 3-oxa-allylic cation species by the central Mo(VI) atom.
View MoreContact:+86-25-85281586
Address:13F,Bld2#,South of Longpan Road
Zhejiang Linhai Xinhua Chemicals Factory
Contact:0086-13661858911
Address:Xunqiao Development Zone, Linhai, Zhejiang, China
Jinan Decheng Hemu Medical Technology Co.,Ltd.
Contact:+86-531-68650525
Address:NO.554 Zhengfeng Road High-new Technology Development Zone
Hefei TNJ chemical industry co.,ltd
website:https://www.tnjchem.com
Contact:+86-551-65418695
Address:B911 Xincheng Business Center, Qianshan Road, Hefei Anhui China
SuZhou Ascepion Pharmaceuticals, Inc.
Contact:0512-86881668
Address:Building C,68Xingqing Road,Suzhou,China.
Doi:10.1002/chem.201902557
(2019)Doi:10.1039/c39860001452
(1986)Doi:10.1021/ja01646a003
(1954)Doi:10.1002/chem.201700440
(2017)Doi:10.1039/c5ra24541a
(2015)Doi:10.1039/c7ta09741g
(2018)