Chemistry of Materials
Article
(21) Carne-
́
San
́
chez, A.; Imaz, I.; Cano-Sarabia, M.; Maspoch, D. A
REFERENCES
■
Spray-Drying Strategy for Synthesis of Nanoscale Metal−organic
Frameworks and Their Assembly into Hollow Superstructures. Nat.
Chem. 2013, 5, 203−211.
(22) Huo, J.; Aguilera-Sigalat, J.; El-Hankari, S.; Bradshaw, D.
Magnetic MOF Microreactors for Recyclable Size-Selective Biocatal-
ysis. Chem. Sci. 2015, 6, 1938−1943.
(23) Falcaro, P.; Malfatti, L.; Vaccari, L.; Amenitsch, H.; Marmiroli,
B.; Grenci, G.; Innocenzi, P. Fabrication of Advanced Functional
Devices Combining Soft Chemistry with X-Ray Lithography in One
Step. Adv. Mater. 2009, 21, 4932−4936.
(24) Horcajada, P.; Chalati, T.; Serre, C.; Gillet, B.; Sebrie, C.; Baati,
T.; Eubank, J. F.; Heurtaux, D.; Clayette, P.; Kreuz, C.; Chang, J.-S.;
(1) Furukawa, H.; Cordova, K. E.; O'Keeffe, M.; Yaghi, O. M. The
Chemistry and Applications of Metal-Organic Frameworks. Science
2013, 341, 1230444.
(2) Stock, N.; Biswas, S. Synthesis of Metal-Organic Frameworks
(MOFs): Routes to Various MOF Topologies, Morphologies, and
Composites. Chem. Rev. 2012, 112, 933−969.
(3) Hu, Z.; Deibert, B. J.; Li, J. Luminescent Metal−organic
Frameworks for Chemical Sensing and Explosive Detection. Chem. Soc.
Rev. 2014, 43, 5815−5840.
(4) Cui, Y.; Song, R.; Yu, J.; Liu, M.; Wang, Z.; Wu, C.; Yang, Y.;
Wang, Z.; Chen, B.; Qian, G. Dual-Emitting MOF⊃Dye Composite
for Ratiometric Temperature Sensing. Adv. Mater. 2015, 27, 1420−
1425.
(5) Chen, B.; Yang, Y.; Zapata, F.; Lin, G.; Qian, G.; Lobkovsky, E. B.
Luminescent Open Metal Sites within a Metal−Organic Framework
for Sensing Small Molecules. Adv. Mater. 2007, 19, 1693−1696.
(6) Falcaro, P.; Normandin, F.; Takahashi, M.; Scopece, P.;
Amenitsch, H.; Costacurta, S.; Doherty, C. M.; Laird, J. S.; Lay, M.
D. H.; Lisi, F.; Hill, A. J.; Buso, D. Dynamic Control of MOF-5 Crystal
Positioning Using a Magnetic Field. Adv. Mater. 2011, 23, 3901−3906.
(7) Van de Voorde, B.; Bueken, B.; Denayer, J.; De Vos, D.
Adsorptive Separation on Metal−organic Frameworks in the Liquid
Phase. Chem. Soc. Rev. 2014, 43, 5766−5788.
(8) Teufel, J.; Oh, H.; Hirscher, M.; Wahiduzzaman, M.; Zhechkov,
L.; Kuc, A.; Heine, T.; Denysenko, D.; Volkmer, D. MFU-4 - A Metal-
Organic Framework for Highly Effective H2/D2 Separation. Adv.
Mater. 2013, 25, 635−639.
(9) Barea, E.; Montoro, C.; Navarro, J. a R. Toxic Gas Removal −
Metal−organic Frameworks for the Capture and Degradation of Toxic
Gases and Vapours. Chem. Soc. Rev. 2014, 43, 5419−5430.
(10) Ricco, R.; Konstas, K.; Styles, M. J.; Richardson, J. J.; Babarao,
R.; Suzuki, K.; Scopece, P.; Falcaro, P. Lead(II) Uptake by Aluminium
Based Magnetic Framework Composites (MFCs) in Water. J. Mater.
Chem. A 2015, 3, 19822−19831.
(11) Stavila, V.; Talin, A. A.; Allendorf, M. D. MOF-Based Electronic
and Opto-Electronic Devices. Chem. Soc. Rev. 2014, 43, 5994−6010.
(12) Zhang, T.; Lin, W. Metal−organic Frameworks for Artificial
Photosynthesis and Photocatalysis. Chem. Soc. Rev. 2014, 43, 5982−
5993.
́
Hwang, Y. K.; Marsaud, V.; Bories, P.-N.; Cynober, L.; Gil, S.; Ferey,
G.; Couvreur, P.; Gref, R. Porous Metal-Organic-Framework Nano-
scale Carriers as a Potential Platform for Drug Delivery and Imaging.
Nat. Mater. 2010, 9, 172−178.
(25) Chalati, T.; Horcajada, P.; Gref, R.; Couvreur, P.; Serre, C.
Optimisation of the Synthesis of MOF Nanoparticles Made of Flexible
Porous Iron Fumarate MIL-88A. J. Mater. Chem. 2011, 21, 2220−
2227.
(26) Falcaro, P.; Ricco, R.; Yazdi, A.; Imaz, I.; Furukawa, S.;
Maspoch, D.; Ameloot, R.; Evans, J. D.; Doonan, C. J. Application of
Metal and Metal Oxide Nanoparticles@MOFs. Coord. Chem. Rev.
(27) Weinryb, I. The Behavior of Horseradish Peroxidase at High
Hydrogen Peroxide Concentrations. Biochemistry 1966, 5, 2003−2008.
(28) Stasiak-Rozanska, L.; Blazejak, S.; Miklaszewska, A. Application
of Immobilized Cell Preparation Obtained from Biomass of
Gluconacetobacter Xylinus Bacteria in Biotransformation of Glycerol
to Dihydroxyacetone. Acta Sci. Pol., Technol. Aliment 2011, 10, 35−49.
(29) Kwon, D.; Joo, J.; Lee, S.; Jeon, S. Facile and Sensitive Method
for Detecting Cardiac Markers Using Ubiquitous pH Meters. Anal.
Chem. 2013, 85, 12134−12137.
(30) Klibanov, A. M. Why Are Enzymes Less Active in Organic
Solvents than in Water? Trends Biotechnol. 1997, 15, 97−101.
(31) Lykourinou, V.; Chen, Y.; Wang, X.-S.; Meng, L.; Hoang, T.;
Ming, L.-J.; Musselman, R. L.; Ma, S. Immobilization of MP-11 into a
Mesoporous Metal−Organic Framework, MP-11@mesoMOF: A New
Platform for Enzymatic Catalysis. J. Am. Chem. Soc. 2011, 133, 10382−
10385.
(32) Bradshaw, D.; Garai, A.; Huo, J. Metal−organic Framework
Growth at Functional Interfaces: Thin Films and Composites for
Diverse Applications. Chem. Soc. Rev. 2012, 41, 2344−2381.
(33) Faustini, M.; Kim, J.; Jeong, G.-Y.; Kim, J. Y.; Moon, H. R.; Ahn,
W.-S.; Kim, D.-P. Microfluidic Approach toward Continuous and
Ultrafast Synthesis of Metal−Organic Framework Crystals and Hetero
Structures in Confined Microdroplets. J. Am. Chem. Soc. 2013, 135,
14619−14626.
(34) Shieh, F.-K.; Wang, S.-C.; Yen, C.-I.; Wu, C.-C.; Dutta, S.;
Chou, L.-Y.; Morabito, J. V.; Hu, P.; Hsu, M.-H.; Wu, K. C.-W.; Tsung,
C.-K. Imparting Functionality to Biocatalysts via Embedding Enzymes
into Nanoporous Materials by a de Novo Approach: Size-Selective
Sheltering of Catalase in Metal-Organic Framework Microcrystals. J.
Am. Chem. Soc. 2015, 137, 4276−4279.
(13) Ramaswamy, P.; Wong, N. E.; Shimizu, G. K. H. MOFs as
Proton Conductors − Challenges and Opportunities. Chem. Soc. Rev.
2014, 43, 5913−5932.
(14) Liang, K.; Ricco, R.; Doherty, C. M.; Styles, M. J.; Bell, S.; Kirby,
N.; Mudie, S.; Haylock, D.; Hill, A. J.; Doonan, C. J.; Falcaro, P.
Biomimetic Mineralization of Metal-Organic Frameworks as Protective
Coatings for Biomacromolecules. Nat. Commun. 2015, 6, 7240.
́
(15) Tamames-Tabar, C.; García-Marquez, A.; Blanco-Prieto, M. J.;
Serre, C.; Horcajada, P. MOFs in Pharmaceutical Technology. In Bio-
and Bioinspired Nanomaterials; Ruiz-Molina, D., Novio, F., Roscini, C.,
Eds.; Wiley-VCH Verlag GmbH & Co. KGaA: New York, 2014; pp
83−112.
(16) Falcaro, P.; Ricco, R.; Doherty, C. M.; Liang, K.; Hill, A. J.;
Styles, M. J. MOF Positioning Technology and Device Fabrication.
Chem. Soc. Rev. 2014, 43, 5513−5560.
(35) Lyu, F.; Zhang, Y.; Zare, R. N.; Ge, J.; Liu, Z. One-Pot Synthesis
of Protein-Embedded Metal-Organic Frameworks with Enhanced
Biological Activities. Nano Lett. 2014, 14, 5761−5765.
(17) Furukawa, S.; Reboul, J.; Diring, S.; Sumida, K.; Kitagawa, S.
Structuring of Metal−organic Frameworks at the Mesoscopic/
macroscopic Scale. Chem. Soc. Rev. 2014, 43, 5700−5734.
́
(36) Katz, M. J.; Brown, Z. J.; Colon, Y. J.; Siu, P. W.; Scheidt, K. A.;
́
(18) Carne, A.; Carbonell, C.; Imaz, I.; Maspoch, D. Nanoscale
Snurr, R. Q.; Hupp, J. T.; Farha, O. K. A Facile Synthesis of UiO-66,
Metal−organic Materials. Chem. Soc. Rev. 2011, 40, 291−305.
(19) Ameloot, R.; Vermoortele, F.; Vanhove, W.; Roeffaers, M. B. J.;
Sels, B. F.; De Vos, D. E. Interfacial Synthesis of Hollow Metal−
organic Framework Capsules Demonstrating Selective Permeability.
Nat. Chem. 2011, 3, 382−387.
UiO-67 and Their Derivatives. Chem. Commun. 2013, 49, 9449−9451.
̈
(37) Odman, P.; Wellborn, W. B.; Bommarius, A. S. An Enzymatic
Process to α-Ketoglutarate from L-Glutamate: The Coupled System L-
Glutamate dehydrogenase/NADH Oxidase. Tetrahedron: Asymmetry
2004, 15, 2933−2937.
(20) Li, A.-L.; Ke, F.; Qiu, L.-G.; Jiang, X.; Wang, Y.-M.; Tian, X.-Y.
Controllable Synthesis of Metal−organic Framework Hollow Nano-
spheres by a Versatile Step-by-Step Assembly Strategy. CrystEngComm
2013, 15, 3554−3559.
(38) Chance, B.; Maehly, A. C. [136] Assay of Catalases and
Peroxidases. Methods Enzymol. 1955, 2, 764−775.
(39) Tranchemontagne, D. J.; Hunt, J. R.; Yaghi, O. M. Room
Temperature Synthesis of Metal-Organic Frameworks: MOF-5, MOF-
F
Chem. Mater. XXXX, XXX, XXX−XXX