Journal of Organometallic Chemistry p. 207 - 212 (1984)
Update date:2022-08-31
Topics:
Arzoumanian, Henri
Lai, Richard
Metzger, Jacques
Petrignani, Jean-Francois
The interaction of bis(t-butylisocyano)peroxonickel(II) and bis(triphenylphosphine oxide)dibromodioxomolybdenum(VI) in the presence of cyclohexane yields 1,2-dibromocyclohexane as the main product.This result is explained by the prior epoxidation of cyclohexene, followed by its conversion into the 1,2-dibromoalkane. The epoxidation step implies peroxidation of the dioxomolybdenum by the peroxonickel species.It is shown that this occurs by a dioxygen-ligand transfer accompanied by the back transfer of two bromine atom and two triphenylphosphine oxide molecules.
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