Tetrahedron Letters p. 2443 - 2446 (1999)
Update date:2022-08-25
Topics:
Nery, Ana L. P.
Roepke, Sascha
Catalani, Luiz H.
Baader, Wilhelm J.
The synthesis of the protected phenolate-substituted 1,2-dioxetanes 1 and 2, containing the substituent directly linked to the peroxidic ring or separated by a methylene group, is reported. The activation parameters and chemiluminescence quantum yield upon unimolecular and catalyzed decomposition of 1 and 2 are in agreement with the occurrence of an intramolecular CIEEL mechanism in the catalyzed decomposition of these dioxetanes.
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