Journal of Fluorine Chemistry p. 105 - 108 (1991)
Update date:2022-08-11
Topics:
Hu, Chang-Ming
Tu, Ming-Hu
Reduction of polyhalofluoroalkanes with formate in the presence of a catalytic amount of persulfate is described.Such a reagent posseses good selectivity in the reduction of carbon-chlorine bonds.A chain mechanism including carbon dioxide anionic radicals and polyhalofluoroalkyl radicals is proposed.
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