Journal of Organometallic Chemistry p. 457 - 468 (1989)
Update date:2022-08-28
Topics:
Garlaschelli, Luigi
Marchionna, Mario
Iapalucci, Maria Carmela
Longoni, Giuliano
Hydrocarboxylation of isoprene catalyzed by iodocarbonylrhodium derivatives is described.Either 4-methyl-3-pentenoic (pyroterebic) acid or its lactone derivative (γ,γ-dimethyl-γ-butyrolactone) can be selectively produced in high yield depending on the experimental conditions.Spectroscopic evidence indicates the possibe partcipation of H+...Rh(CO)2I- tight ion pairs and/or cisRh(CO)2(H2O)I in the catalysis.The identification of these two new species is based on spectroscopic investigation of the interconversion reactions between solvent-separated
Kunshan Yalong Trading Co,.Ltd
Contact:86-512-57621185
Address:805-807 Room Hongqiao Mansion ,1088 West Qianjin Road, Kunshan, Jiangsu,China
Taizhou volsen chemical Co., Ltd
website:http://www.volsenchem.com
Contact:+86-576-88869393
Address:Jiaojiang District, Taizhou, Zhejiang, China.
Zouping Mingxing Chemical Co.,Ltd.
website:http://www.zoutong.com.cn
Contact:86-543-2240068 2240067
Address:428 Daixi Third Road Zouping County Shandong Province China
Lianyungang Ningkang Chemical Co., Ltd
Contact:.+86-518-88588008
Address:http://www.chemnk.com
Dalian RSD International Trade Co.,Ltd.
Contact:86-22-60875058 58610575
Address:Wantong International Areas, Hongqiao District, Tianjin, China.China
Doi:10.1039/DT9760000435
()Doi:10.1021/ja00423a026
(1976)Doi:10.1039/a805319g
(1999)Doi:10.1016/S0040-4039(98)01547-0
(1998)Doi:10.1134/S1070363207020119
(2007)Doi:10.1039/c4ra08084j
(2014)