Chemistry of Heterocyclic Compounds p. 740 - 745 (1986)
Update date:2022-08-11
Topics:
Shafran, Yu. M.
Bakulev, V. A.
Mokrushin, V. S.
Alekseev, S. G.
Lebedev, A. T.
Sharbatyan, P. A.
1,2,3-Triazol-5-olates are formed in the reaction of diazomalonodiamide and 2-diazo-2-cyanoacetic acid amide and N-methylamide with sodium ethoxide, triethylamine, and ammonia.The products of the reaction of 2-diazo-2-cyanoacetamide with primary amines are mixtures of 4-cyano-1,2,3-triazol-5-olates and 5-amino-1-alkyl-1,2,3-triazole-4-carboxamides.
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(2012)