Paper
RSC Advances
impregnation method were applied in the oxidation of HMF to 14 G. J. ten Brink, I. Arends and R. A. Sheldon, Science, 2000,
FDCA at room temperature. The Pt/CeO2 showed a poor catalytic 287, 1636–1639.
performance towards the reaction, which was similar to the Pt 15 Z. Zhang, J. Zhen, B. Liu, K. Lv and K. Deng, Green Chem.,
sol. The Pt/Ce0.8Bi0.2O2ꢀd catalyst showed an excellent catalytic
activity. 98% yield of FDCA was obtained over the Pt/Ce0.8Bi0.2
O2ꢀd catalyst within 30 min and the catalyst was well reused for
2015, 17, 1308–1317.
16 X. Wan, C. Zhou, J. Chen, W. Deng, Q. Zhang, Y. Yang and
Y. Wang, ACS Catal., 2014, 4, 2175–2185.
-
ve times without much loss of the catalytic activity. An appro- 17 M. Tamura and K. Tomishige, Angew. Chem., Int. Ed., 2014,
priate reaction mechanism was suggested. The natural proper- 53, 1–5.
ties of the Pt NPs and the ceria-based support were remained 18 N. Lopez, T. V. W. Janssens, B. S. Clausen, Y. Xu,
aer their combination. The unique oxygen activation function
of the Bi-doped ceria played an essential role during the catalytic
M. Mavrikakis, T. Bligaard and J. K. Norskov, J. Catal.,
2004, 223, 232–235.
oxidation process. It changed the performance of the ceria-based 19 B. T. Teng, J. J. Lang, X. D. Wen, C. Zhang, M. H. Fan and
material supported Pt catalyst towards catalytic alcohol oxida- H. G. Harris, J. Phys. Chem. C, 2013, 117, 18986–18993.
tion thoroughly. The catalyst should also be efficient for the 20 A. Trovarelli, Catal. Rev.: Sci. Eng., 1996, 38, 439–520.
oxidation of other alcohols or aldehydes at moderate reaction 21 F. Esch, S. Fabris, L. Zhou, T. Montini, C. Africh,
conditions. The catalytic activity could be further improved by
modulating the Pt particle size.
P. Fornasiero, G. Comelli and R. Rosei, Science, 2005, 309,
752–755.
22 Z. Miao, Y. Zhang, X. Pan, T. Wu, B. Zhang, J. Li, T. Yi,
Z. Zhang and X. Yang, Catal. Sci. Technol., 2015, 5, 1314–
1322.
Acknowledgements
The authors thank the National Natural Science Foundation of
China. This work was supported by the National Natural Science
Foundation of China (21273221).
23 N. Dimitratos, A. Villa, D. Wang, F. Porta, D. Su and L. Prati,
J. Catal., 2006, 244, 113–121.
24 R. Sahu and P. Dhepe, React. Kinet., Mech. Catal., 2014, 1–15.
25 R. M. Rioux, H. Song, J. D. Hoefelmeyer, P. Yang and
G. A. Somorjai, J. Phys. Chem. B, 2005, 109, 2192–2202.
26 T. Wu, X. Pan, Y. Zhang, Z. Miao, B. Zhang, J. Li and X. Yang,
J. Phys. Chem. Lett., 2014, 5, 2479–2483.
27 S. Siankevich, G. Savoglidis, Z. Fei, G. Laurenczy,
D. T. L. Alexander, N. Yan and P. J. Dyson, J. Catal., 2014,
315, 67–74.
28 N. Imanaka, T. Masui, K. Koyabu, K. Minami and T. Egawa,
Adv. Mater., 2007, 19, 1608–1611.
29 D. Jiang, W. Wang, E. Gao, L. Zhang and S. Sun, J. Phys.
Chem. C, 2013, 117, 24242–24249.
Notes and references
1 A. Corma, S. Iborra and A. Velty, Chem. Rev., 2007, 107, 2411–
2502.
2 T. Werpy and G. Petersen, Top Value Added Chemicals from
Biomass, Pacic Northwest National Laboratory, 2004, vol.
1, p. 27.
3 P. Gallezot, Green Chem., 2007, 9, 295–302.
4 D. A. Kotadia and S. S. Soni, Catal. Sci. Technol., 2013, 3, 469–
474.
5 C. Moreau, M. N. Belgacem and A. Gandini, Top. Catal., 2004,
27, 11–30.
30 B. N. Zope, D. D. Hibbitts, M. Neurock and R. J. Davis,
Science, 2010, 330, 74–78.
6 S. Dutta, S. De and B. Saha, ChemPlusChem, 2012, 77, 259–
272.
31 B. Liu, Y. Ren and Z. Zhang, Green Chem., 2015, DOI:
10.1039/c4gc02019g.
7 S. Thiyagarajan, W. Vogelzang, R. J. I. Knoop, A. E. Frissen,
J. van Haveren and D. S. van Es, Green Chem., 2014, 16,
1957–1966.
8 S. E. Davis, L. R. Houk, E. C. Tamargo, A. K. Datye and
R. J. Davis, Catal. Today, 2011, 160, 55–60.
9 O. Casanova, S. Iborra and A. Corma, ChemSusChem, 2009, 2,
1138–1144.
32 S. E. Davis, B. N. Zope and R. J. Davis, Green Chem., 2012, 14,
143–147.
33 Y. Zhao, B.-T. Teng, X.-D. Wen, Y. Zhao, Q.-P. Chen,
L.-H. Zhao and M.-F. Luo, J. Phys. Chem. C, 2012, 116,
15986–15991.
34 C. Li, K. Domen, K. Maruya and T. Onishi, J. Am. Chem. Soc.,
1989, 111, 7683–7687.
10 P. Verdeguer, N. Merat and A. Gaset, J. Mol. Catal., 1993, 85,
327–344.
35 X. Li and A. A. Gewirth, J. Am. Chem. Soc., 2003, 125, 7086–
7099.
11 Z. Zhang, B. Liu, K. Lv, J. Sun and K. Deng, Green Chem.,
2014, 16, 2762–2770.
12 T. Pasini, M. Piccinini, M. Blosi, R. Bonelli, S. Albonetti,
N. Dimitratos, J. A. Lopez-Sanchez, M. Sankar, Q. He,
C. J. Kiely, G. J. Hutchings and F. Cavani, Green Chem.,
2011, 13, 2091–2099.
36 B. G. M. Rocha, M. L. Kuznetsov, Y. N. Kozlov,
A. J. L. Pombeiro and G. B. Shul'pin, Catal. Sci. Technol.,
2015, DOI: 10.1039/c4cy01651c.
37 A. Abad, P. Concepcion, A. Corma and H. Garcia, Angew.
Chem., Int. Ed., 2005, 44, 4066–4069.
13 T. Mallat and A. Baiker, Chem. Rev., 2004, 104, 3037–3058.
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