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Green Chemistry
Page 10 of 12
DOI: 10.1039/C7GC01116D
ARTICLE
Journal Name
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Conclusions
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9
In summary, we report the first MPIL-supported Au-Pd alloy
NPs that act as the recyclable heterogeneous catalyst for the
water-mediated aerobic oxidation of HMF to FDCA with
atmospheric O2. The MPIL-based ionic copolymers with
tunable wettability were synthesized through varying the
cross-linkers with different hydrophilic and hydrophobic
properties, thus providing the encouraging potentiality to
control the surface wettafbility of supported metal NPs from
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10 molecular scale designation. Au-Pd alloy NPs were supported
11 on MPILs through an ion-exchange with successive
12 reduction. In this process, the metal precursors were
13 molecular-dispersed on the supports in the absence of any
14 steric stabilizer, not only simplifying the preparation but also
15 benefiting the alloy control and the achievement of uniform
16 stable alloy NPs. High yield, large TON value plus well
17 reusability were achieved on the hydrophilic MPIL-supported
18 Au-Pd alloy NPs with controlled composition. The hydrophilic
19 surface dominated the catalytic performance and synergistic
20 alloy effect between Au and Pd exhibited higher activity than
21 monometallic NPs. This work provides an efficient
22 heterogeneous catalyst for the synthesis of FDCA from HMF
23 and shows that MPILs are promising supports towards active
24 and stable alloy NPs.
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25 Acknowledgements
88
26 The authors thank greatly the National Natural Science
27 Foundation of China (Nos. U1662107, 21476109, 21136005
28 and 21303084), Jiangsu Provincial Science Foundation for
29 Youths (No. BK20130921 and BK20160976), Specialized
30 Research Fund for the Doctoral Program of Higher Education
31 (No. 20133221120002), the China Postdoctoral Science
32 Foundation (2016M590447), the Project of Priority Academic
33 Program Development of Jiangsu Higher Education
34 Institutions (PAPD) and the Scientific Research and
35 Innovation Project for College Graduates of Jiangsu Province
36 (KYCX17_0965).
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