Research on Chemical Intermediates p. 7115 - 7124 (2015)
Update date:2022-08-04
Topics:
Huang, Jian-Gang
Guo, Ying
Jiang, Jian-An
Liu, Hong-Wei
Ji, Ya-Fei
An undecorated Co(OAc)2-catalyzed aerobic oxidation system has been reported that enables direct transformation of 4-benzylphenols into the corresponding 4-hydroxybenzophenones. The procedure is especially suitable for electron-withdrawing group-containing substrates, which are commonly inefficient to conduct this category of oxidation. Based on well-defined p-benzoquinone methides and the confirmed ethereal intermediate, a plausible mechanism was depicted.
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