Organometallics p. 430 - 432 (1987)
Update date:2022-08-11
Topics:
Goldberg, Karen I.
Bergman, Robert G.
Alkylation of the rhenium metalate Li[CpRe-(CO)2(COCH3)] (1) can be controlled to give either the Fischer carbene complex Cp(CO)2Re=C(OCH3)(CH3) or the new alkyl aryl complex Cp(CO)2Re(COCH3)(CH3) (2). Photochemical decomposition of 2 under 20 atm of CO leads to 2,3-butanedione; evidence is presented that the diketone is produced by formation and carbonylation of free methyl radicals.
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(1985)