Journal of Fluorine Chemistry p. 59 - 68 (1993)
Update date:2022-08-11
Topics:
Weigert, F. J.
Davis, R. F.
The 2+2 cycloadducts of fluorinated olefins other than tetrafluoroethylene and hydrocarbon dienes also ring-expand and eliminate two moles hydrogen halide to form aromatic products.The hydrogen halide eliminated from chlorofluoroolefin adducts depends on the solid present during the aromatization.Alumina and other accelerators favor elimination of HF, while HCl evolves in the presence of inert solids such as SiC.The aromatics derived from hexafluoropropane adducts generally have the more sterically hindered regiochemistry.Alumina promotes extrusion of difluorocarbene from trifluoromethylcyclobutanes leading to fluorobenzenes rather than benzotrifluorides.Carbon accelerates these aromatizations without difluorocarbene extrusion.
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