Journal of Fluorine Chemistry p. 71 - 78 (1994)
Update date:2022-08-18
Topics:
Boutevin, B.
Guida-Pietrasanta, F.
Ratsimihety, A.
Caporiccio, G.
The hydrosilylation of various fluorinated olefins and of a diene with different chlorosilanes and with a tri(fluoroalkyl)silane, in the presence of a peroxide or a Pt catalyst, is reported.The reactivity is influenced considerably by the structure of the silane and of the fluorinated olefin.The following (fluoroalkyl)chlorosilanes and (fluoroalkyl)-α,ω-chlorodisilanes are described; C6F13(CH2)nSiR1R2Cl where n = 2 or 3 and (ClR1R2SiC2H4C3F6)2 with R1 = R2 = Cl, R1 = Cl and R2 = CH3 or C2H4CF3, R1 = R2 = CH3 and R1 = CH3 and R2 = C6H5.Three new tetra(fluoroalkyl)silanes have also been synthesized.All the products were characterized by 1H, 19F and 29Si NMR spectroscopy.
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