Magnetic Resonance in Chemistry p. 719 - 724 (1989)
Update date:2022-08-16
Topics:
Diaz, Eduardo
Barrios, Hector
Ortiz, Benjamin
Sanchez-Obregon, Ruben
Yuste, Francisco
et al.
The reaction of dibenzalcyclohexanone with hydroxylamine hydrochloride affords three compounds: the oxime of 2-benzylidenecyclohexanone (2), 3-phenyl-7-benzylidene-3,3a,4,5,6,7-hexahydro-2,1-benzisoxazole (3) and 3-phenyl-3,3a,4,5,6,7-hexahydro-2,1-benzisoxazole-7-spiro-2'-(3'-phenylaziridine) (4).Their structures were decuded by 2D NMR analysis.Single-crystal x-ray diffraction was used to confirm the structure and stereochemistry of 4.A possible mechanism for this reaction is proposed.KEY WORDS - 2D NMR spectroscopy X-ray structure Dibenzalcyclohexanone Hydroxylamine hydrochloride
View MoreJinan Boss Chemical Industry Co., Ltd.
website:http://www.chemboss.com.cn
Contact:+86-531-58591595
Address:No2.Hualong Road, Jinan, China
Zhengzhou Xinlian Chemical Tech Co. ,Ltd
Contact:0371-65771781 021-52042910
Address:H Part, Building I, No. 700 Gonglu Road, Pudong New Area, Shanghai
Shangyu Sanhechemicals Co.,LTD.
Contact:86-0571-56696839
Address:Num.2952,Nanhuan Road,Binjiang District,Hangzhou,China
Hangzhou Yingshanhua Pigment Chemicals Co.,Ltd.
Contact:+86-0150-58101658
Address:Nanyang Economic DevelopmentZong,Xiaoshan,Hangzhou,China
Contact:86-571-61063068
Address:LINAN
Doi:10.1016/j.ejmech.2015.01.009
(2015)Doi:10.1016/j.tetlet.2014.10.057
(2014)Doi:10.1016/j.tetlet.2015.10.088
(2015)Doi:10.1002/asia.200900420
(2010)Doi:10.1002/chem.202005246
(2021)Doi:10.1055/s-2005-863733
(2005)