Journal of the American Chemical Society p. 1612 - 1616 (1982)
Update date:2022-08-29
Topics:
Young, Paul R.
Hsieh, Li-Shan
The iodine oxidation of N-acetylmethionine methyl ester is catalyzed by carboxylic acid buffers.At very low concentrations, the reaction is first order with respect to buffer and follows an iodide dependence that can be described as inverse squared, changing to invers cubed as the iodide concentration is increased.This iodide dependence is observed at all buffer concentrations examined, although the transition from inverse squared to inverse cubed occurs at higher iodide concentrations as the buffer concentration is increasd.As the buffer concentration is increased, the observed rate constants become dependent upon
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