Tetrahedron p. 9955 - 9972 (1993)
Update date:2022-08-17
Topics:
Knolker
Foitzik
Graf
Pannek
Jones
The Lewis-acid-promoted reaction of allyltrimethylsilane with enones is shown to afford the 3-allyl ketone derivatives (Sakurai products) along with the trimethylsilylcyclopentanes ([3+2] cycloaddition products). The stereochemistry of the [3+2] cycloaddi
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